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Merck
CN

663816

1,4-Benzenediboronic acid bis(pinacol) ester

97%

Synonym(s):

1,4-Benzenediboronic acid dipinacol ester, 1,4-Bis(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzene, 1,4-Phenylenebis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane), cyclic bis(tetramethylethylene) ester p-Benzenediboronic acid

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About This Item

Empirical Formula (Hill Notation):
C18H28B2O4
CAS Number:
99770-93-1
Molecular Weight:
330.03
NACRES:
NA.22
PubChem Substance ID:
24884661
UNSPSC Code:
12352103
MDL number:
MFCD08276852

Key Documents

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Product Name

1,4-Benzenediboronic acid bis(pinacol) ester, 97%

InChI

1S/C18H28B2O4/c1-15(2)16(3,4)22-19(21-15)13-9-11-14(12-10-13)20-23-17(5,6)18(7,8)24-20/h9-12H,1-8H3

SMILES string

CC1(C)OB(OC1(C)C)c2ccc(cc2)B3OC(C)(C)C(C)(C)O3

InChI key

UOJCDDLTVQJPGH-UHFFFAOYSA-N

assay

97%

form

solid

mp

241-245 °C

Quality Level

100

Related Categories

Application

Reagent used for
  • Suzuki-Miyaura cross-coupling reactions and polymerizations

Reagent used in Prepration of
  • Efficient solar cell photoelectric polymers
  • Field-effect transistors and photovoltaic cells
  • Fluorescent compounds and materials such as Blue OLED devices, Blue Polymeric Light Emitting Diodes, and White LEDs

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKCH6566
MKBW8502V
MKBR8880V
MKBH3593V
MKBD8034V

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Small band gap copolymers based on furan and diketopyrrolopyrrole for field-effect transistors and photovoltaic cells
Bijleveld, J. C.; et al.
Journal of Materials Chemistry, 21, 1600-1606 (2011)
Efficient solar cells based on an easily accessible diketopyrrolopyrrole polymer
Bijleveld, J. C.; et al.
Advanced Materials, 22, 242-246 (2010)
Preparation of p-conjugated polymer/silica hybrids particle and their application to white light emitting diode
Kubo, M.; et al.
Kobunshi Ronbunshu, 65, 427-432 (2008)
Liwen Hu et al.
Journal of materials chemistry. B, 8(46), 10609-10615 (2020-11-03)
In this work, an anionic conjugated polyelectrolyte (PCP-SO3K), in which the backbone contains alternating 4,4-bis-alkyl-4H-cyclopenta-[2,1-b;3,4-b']-dithiophene and benzene structural units and the charges are provided by pendant sulfonate groups, was synthesized. The ionic nature of PCP-SO3K renders it soluble in water
Triphenylene-Based Polymers for Blue Polymeric Light Emitting Diodes
Saleh, M.; et al.
Macromolecules, 43, 137-143 (2010)
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