664073
(S)-(+)-2,3,7,7a-Tetrahydro-7a-methyl-1H-indene-1,5(6H)-dione
97%
Synonym(s):
(+)-5,6,7,8-Tetrahydro-8-methylindan-1,5-dione, (+)-7,7a-Dihydro-7α, β-methyl-1,5(6H)-indandione, (S)-(+)-Hajos-Parrish diketone, (S)-Hajos dione, (S)-Hajos ketone, (S)-Hajos-Wiechert ketone
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About This Item
Quality Segment
assay
97%
form
solid
mp
57-64 °C
functional group
ketone
SMILES string
C[C@]12CCC(=O)C=C1CCC2=O
InChI
1S/C10H12O2/c1-10-5-4-8(11)6-7(10)2-3-9(10)12/h6H,2-5H2,1H3/t10-/m0/s1
InChI key
FNYAZSZTENLTRT-JTQLQIEISA-N
Application
- The total synthesis of steroidal alkaloids cortistatins.
- The stereoselective preparation of hydroanthracenol and related polycyclic compounds via Ti(Oi-Pr)4-promoted photoenolization Diels-Alder reaction.
- The synthesis of γ,γ-disubstituted allyldiboron compounds by reacting with allylic 1,1-diboronate reagents via Cu-catalyzed borylation and 1,2-addition reaction.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
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