665134
Oxotrichloro[bis(diphenylphosphino)methane]rhenium(V)
Synonym(s):
Trichloro[methylenebis[diphenylphosphine]-P,P′]oxorhenium
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About This Item
Empirical Formula (Hill Notation):
C25H22Cl3OP2Re
CAS Number:
Molecular Weight:
692.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
InChI
1S/C25H22P2.3ClH.O.Re/c1-5-13-22(14-6-1)26(23-15-7-2-8-16-23)21-27(24-17-9-3-10-18-24)25-19-11-4-12-20-25;;;;;/h1-20H,21H2;3*1H;;/q;;;;;+3/p-3
SMILES string
Cl[Re](Cl)(Cl)=O.C(P(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4
InChI key
SAVOOVLDSRTAGJ-UHFFFAOYSA-K
form
solid
reaction suitability
core: rhenium, reagent type: catalyst
Application
Catalyst for:
- Epoxidation of olefins using hydrogen peroxide activated bicarbonate as an oxidant
- Efficient reduction of aromatic sulfoxides
- Regioselective coupling of propargyl alcohols with sulfonamides and carbamates
- Cycloisomerization reactions
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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