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Merck
CN

665142

Tris(triphenylphosphinegold)oxonium tetrafluoroborate

solid

Synonym(s):

Oxotris((triphenylphosphine)gold) tetrafluoroborate, Oxotris(triphenylphosphine)trigold tetrafluoroborate, Tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate

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About This Item

Empirical Formula (Hill Notation):
C54H45P3OAu3BF4
CAS Number:
Molecular Weight:
1480.56
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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Product Name

Tris(triphenylphosphinegold)oxonium tetrafluoroborate,

form

solid

Quality Segment

reaction suitability

core: gold, reagent type: catalyst

SMILES string

[Au][O+]([Au])[Au].F[B-](F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1

InChI key

HTZIGJMQHZNAQD-UHFFFAOYSA-N

Application

Used in a variety of gold catalyzed reactions including propargyl Claisen rearrangements.


pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves



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