668923
Di-μ-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimino-κN)methyl]phenyl-κC]palladium dimer
97%
Synonym(s):
Nájera Catalyst I, Di-chlorobis[5-chloro-2-[(4-chlorophenyl)(hydroxyimino)methyl]phenyl-C]di-palladium
Select a Size
About This Item
SMILES string
O\N=C(/c1ccc(Cl)cc1)c2ccc(Cl)cc2[Pd]Cl.O\N=C(/c3ccc(Cl)cc3)c4ccc(Cl)cc4[Pd]Cl
InChI
1S/2C13H8Cl2NO.2ClH.2Pd/c2*14-11-5-1-9(2-6-11)13(16-17)10-3-7-12(15)8-4-10;;;;/h2*1-3,5-8,17H;2*1H;;/q;;;;2*+1/p-2/b2*16-13+;;;;
InChI key
GIMFEGPTUHULMU-VAABLSLRSA-L
assay
97%
form
solid
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
Application
- Suzuki coupling
- Suzuki-Miyaura coupling
- Najera palladacycle-catalyzed intermolecular Heck reaction of Morita-Baylis-Hillman adducts
- Hiyama cross-coupling
- Palladium-catalyzed acylation of terminal alkynes with acid chlorides
- Copper and amine free Sonogashira coupling reaction
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Articles
Palladacyclic catalysts by Bedford's group facilitate coupling reactions with low catalyst loadings and challenging aryl chlorides.
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service