668966
(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl
97%
Synonym(s):
(R)-Tol-BINAP
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About This Item
Product Name
(R)-(+)-2,2′-Bis(di-p-tolylphosphino)-1,1′-binaphthyl, 97%
InChI
1S/C48H40P2/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42/h5-32H,1-4H3
SMILES string
Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
InChI key
IOPQYDKQISFMJI-UHFFFAOYSA-N
assay
97%
form
solid
mp
254-258 °C
functional group
phosphine
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Application
Reactant serving as a precursor for:
- Catalysts used for reductive amination of ketones
- Rh(I)-catalyst for hydrogenation of acetamidoacrylic acid derivatives
- Chiral platinum catalysts for asymmetric Baeyer-Villiger oxidation of cyclic ketones
- CuI-Tol-BINAP catalysts for enantioselective Michael reactions of Grignard reagents to unsaturated esters
- BINAP Pt Dications for cation trapping
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
The Baeyer-Villiger oxidation is the oxidative cleavage of a carbon-carbon bond adjacent to a carbonyl, which converts the ketones to esters and the cyclic ketones to lactones.
We present an article concerning BINAP/SEGPHOS® Ligands and Complexes.
Baeyer-Villiger氧化是与羰基相邻的碳-碳键的氧化裂解，其可将酮转化为酯、环酮转化为内酯。
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