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Merck
CN

671800

Di(1-adamantyl)benzylphosphine

95%, solid

Synonym(s):

cataCXium® ABn

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About This Item

Empirical Formula (Hill Notation):
C27H37P
CAS Number:
Molecular Weight:
392.56
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
Beilstein/REAXYS Number:
9359745
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Product Name

Di(1-adamantyl)benzylphosphine, 95%

InChI

1S/C27H37P/c1-2-4-19(5-3-1)18-28(26-12-20-6-21(13-26)8-22(7-20)14-26)27-15-23-9-24(16-27)11-25(10-23)17-27/h1-5,20-25H,6-18H2/t20-,21+,22-,23-,24+,25-,26-,27-

SMILES string

C1[C@H]2C[C@H]3C[C@@H]1C[C@@](C2)(C3)P(Cc4ccccc4)[C@@]56C[C@@H]7C[C@@H](C[C@@H](C7)C5)C6

InChI key

ANIAFEJRWQDKDV-ANIFQACUSA-N

assay

95%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Asymmetric synthesis

functional group

phosphine

Quality Level

General description

sold in collaboration with Solvias AG

Application

Catalyst for:
  • Sonogashira coupling reaction
  • Ruthenium-catalyzed amination of secondary alcohols. with ammonia
  • Rhodium-catalyzed regioselective hydroformylation of alkenes
  • Reductive carbonylation
  • Suzuki coupling reaction

Legal Information

US7148176
cataCXium is a registered trademark of Umicore AG & Co. KG

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Articles

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

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