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Merck
CN

672459

2-(Dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole

95%

Synonym(s):

cataCXium® POMeCy

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About This Item

Empirical Formula (Hill Notation):
C23H32NOP
CAS Number:
Molecular Weight:
369.48
PubChem Substance ID:
UNSPSC Code:
12352005
Beilstein/REAXYS Number:
9656639
MDL number:
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SMILES string

COc1ccccc1-n2cccc2P(C3CCCCC3)C4CCCCC4

InChI

1S/C23H32NOP/c1-25-22-16-9-8-15-21(22)24-18-10-17-23(24)26(19-11-4-2-5-12-19)20-13-6-3-7-14-20/h8-10,15-20H,2-7,11-14H2,1H3

InChI key

JUZAKZRALSJLOV-UHFFFAOYSA-N

assay

95%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Asymmetric synthesis

functional group

phosphine

General description

sold in collaboration with Solvias AG

Application

  • Used as ligand in arylation reaction with bromobenzene, and phosphorylation reactions with chlorophosphines
  • Cocatalyst in palladium-catalyzed Suzuki coupling reactions

Legal Information

WO 2004/101581
cataCXium is a registered trademark of Umicore AG & Co. KG

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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