672483
(S)-(−)-1-(2,4,6-Triisopropylphenyl)ethanol
≥98.5% (HPLC)
Synonym(s):
(S)-Stericol®
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About This Item
Empirical Formula (Hill Notation):
C17H28O
CAS Number:
Molecular Weight:
248.40
UNSPSC Code:
12352002
PubChem Substance ID:
MDL number:
Assay:
≥98.5% (HPLC)
Quality Level
assay
≥98.5% (HPLC)
optical purity
enantiomeric ratio: ≥98:2 (HPLC)
SMILES string
CC(C)c1cc(C(C)C)c([C@H](C)O)c(c1)C(C)C
InChI
1S/C17H28O/c1-10(2)14-8-15(11(3)4)17(13(7)18)16(9-14)12(5)6/h8-13,18H,1-7H3/t13-/m0/s1
InChI key
VYKPQIIFUMKNLF-ZDUSSCGKSA-N
Application
Legal Information
Stericol is a registered trademark of Université Joseph Fourier
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Regulatory Information
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A New Asymmetric Carbon-Carbon Bond Forming Reaction: Four-Component Stereoselective Synthesis of (Z)-4,6-Dihydroxy-3-methylalk-2-enyl Methyl Sulfones This work was supported by the Swiss National Science Foundation.
Narkevitch et al.
Angewandte Chemie (International ed. in English), 39(10), 1806-1808 (2000-08-10)
Hamel, M., et al.
Tetrahedron Asymmetry, 16, 3406-3415 (2005)
Caroline Roche et al.
The Journal of organic chemistry, 70(21), 8352-8363 (2005-10-08)
Three natural pyrrolizidines, (+)-amphorogynines A and D and (+)-retronecine, have been prepared from a common lactam intermediate. This central compound, in turn, was synthesized in diastereomerically enriched form through a highly selective [2 + 2]-cycloaddition of dichloroketene with a chiral
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