673269
Sodium dimethylphenylsilanolate hydrate
97%
Synonym(s):
Phenyl(dimethyl)silanolate sodium salt
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About This Item
Linear Formula:
(C6H5)Si(ONa)(CH3)2 · xH2O
Molecular Weight:
174.25 (anhydrous basis)
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
Assay
97%
form
solid
mp
197-218 °C
SMILES string
[Na+].[H]O[H].C[Si](C)([O-])c1ccccc1
InChI
1S/C8H11OSi.Na.H2O/c1-10(2,9)8-6-4-3-5-7-8;;/h3-7H,1-2H3;;1H2/q-1;+1;
InChI key
GTSOGRDRMFDZQL-UHFFFAOYSA-N
Application
A useful silicon nucleophile for Pd-catalyzed cross-coupling.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)
Articles
Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.
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