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About This Item
Linear Formula:
(C6H5)Si(ONa)(CH3)2 · xH2O
Molecular Weight:
174.25 (anhydrous basis)
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C8H11OSi.Na.H2O/c1-10(2,9)8-6-4-3-5-7-8;;/h3-7H,1-2H3;;1H2/q-1;+1;
SMILES string
[Na+].[H]O[H].C[Si](C)([O-])c1ccccc1
InChI key
GTSOGRDRMFDZQL-UHFFFAOYSA-N
assay
97%
form
solid
mp
197-218 °C
Application
A useful silicon nucleophile for Pd-catalyzed cross-coupling.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Denmark, S. E.; Ober, M. H.
Aldrichimica Acta, 36, 75-75 (2003)
Articles
Pd-catalyzed cross-coupling of silicon compounds offers an alternative in synthetic chemistry.
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