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Merck
CN

679488

Rhodium nanoparticles entrapped in aluminum hydroxide matrix preparation

5 wt. % loading

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About This Item

Linear Formula:
Rh/AlO(OH)
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
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reaction suitability

core: rhodium, reagent type: catalyst

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

Application

Supported Rh nanoparticle catalyst.

Used for promoting photocatalytic hydrogen production

Catalyst for:
  • CO oxidation
  • Electrocatalytic applications
  • Arene hydrogenation


pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Supported rhodium oxide nanoparticles as highly active CO oxidation catalysts.
D A J Michel Ligthart et al.
Angewandte Chemie (International ed. in English), 50(23), 5306-5310 (2011-04-22)
Katsuya Shimura et al.
Chemical communications (Cambridge, England), 47(31), 8958-8960 (2011-07-08)
Photodeposition of a Rh cocatalyst under atmospheric conditions could simultaneously provide both Rh metal and oxide nanoparticles on a K(2)Ti(6)O(13) photocatalyst, both of which cooperatively promoted the photocatalytic hydrogen production from water and methane.
Ryan R Dykeman et al.
Inorganic chemistry, 50(3), 717-719 (2011-01-07)
The imidazolium functionalized bipyridine compounds, {4,4'-bis[7-(2,3-dimethylimidazolium)heptyl]-2,2'-bipyridine}(2+) ([BIHB](2+)) and {4,4'-bis[(1,2-dimethylimidazolium)methyl]-2,2'-bipyridine}(2+) ([BIMB](2+)), were prepared and used as Rh nanoparticle stabilizers. The dispersed Rh nanoparticles were used as catalysts in the biphasic hydrogenation of various arene substrates. The catalytic activity was strongly influenced



Global Trade Item Number

SKUGTIN
679488-1G04061826700303