680826
(–)-(S)-N-((R)-3,3-Dimethylbutan-2-yl)-3,3-dimethyl-2-((1-methyl-1H-imidazol-2-yl)methylamino)butanamide
97%
Synonym(s):
Hoveyda-Snapper Desymmetrization Catalyst
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About This Item
Empirical Formula (Hill Notation):
C17H32N4O
CAS Number:
Molecular Weight:
308.46
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352005
MDL number:
InChI
1S/C17H32N4O/c1-12(16(2,3)4)20-15(22)14(17(5,6)7)19-11-13-18-9-10-21(13)8/h9-10,12,14,19H,11H2,1-8H3,(H,20,22)/t12-,14-/m1/s1
SMILES string
C[C@@H](NC(=O)[C@@H](NCc1nccn1C)C(C)(C)C)C(C)(C)C
InChI key
QOCLPFRRAGRCEM-TZMCWYRMSA-N
assay
97%
form
solid
optical activity
[α]22/D -79°, c = 1 in chloroform
mp
130-134 °C
Quality Level
Application
Useful organocatalyst in the desymmetrization of meso diols.
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Yu Zhao et al.
Nature, 443(7107), 67-70 (2006-09-08)
Reliable, selective and environmentally friendly chemical transformations are crucial to the development of new therapeutics and the design of novel materials. Chiral catalysts that can be easily prepared and used to obtain organic molecules of high enantiomeric purity are critical
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