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680834

N-(2,2,2-Trichloroethoxysulfonyl)urea

Name: <I>N</I>-(2,2,2-Trichloroethoxysulfonyl)urea
Brand: ALDRICH

96%

Synonym(s):

Aminocarbonylsulfamic acid, 3,3,3-trichloroethoxy ester, Tces-Urea

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About This Item

Linear Formula:

NH₂CONHSO₂OCH₂CCl₃

CAS Number:

882739-31-3

Molecular Weight:

271.51

NACRES:

NA.22

PubChem Substance ID:

24885597

UNSPSC Code:

12352101

MDL number:

MFCD09265147

Assay:

96%

Form:

solid

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Properties

assay

96%

form

solid

mp

161-165 °C

SMILES string

NC(=O)NS(=O)(=O)OCC(Cl)(Cl)Cl

InChI

1S/C3H5Cl3N2O4S/c4-3(5,6)1-12-13(10,11)8-2(7)9/h1H2,(H3,7,8,9)

InChI key

QYUJBOJJEGIBCJ-UHFFFAOYSA-N

Description

Application

Reactant for oxidative C-H amination reactions

Reagent for Rh-catalyzed urea formation.

Reagent for cyclic urea synthesis.

pictograms

GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

08929AH

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Expanding the substrate scope for C-H amination reactions: oxidative cyclization of urea and guanidine derivatives.

Mihyong Kim et al.

Organic letters, 8(6), 1073-1076 (2006-03-10)

[reaction: see text] Oxidative C-H amination of N-trichloroethoxysulfonyl-protected ureas and guanidines is demonstrated to proceed in high yield for tertiary and benzylic-derived substrates. The success of these reactions is predicated on the choice of the electron-withdrawn 2,2,2-trichloroethoxysulfonyl (Tces) protecting group

Global Trade Item Number

SKU	GTIN
680834-1G	04061826733615
680834-5G	04061833499788