686506
m-Carborane-9-thiol
97%
Synonym(s):
1,7-Dicarba-closo-dodecaborane-9-yl-thiol, 9-Mercapto-1,7-dicarbadodecaborane (12)
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About This Item
Empirical Formula (Hill Notation):
C2H12B10S
CAS Number:
Molecular Weight:
176.29
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C2H12B10S/c13-12-7-2-3-1(6-11-12)4-8-10-9-5-2/h1-11,13H/t1-,2+/m1/s1
SMILES string
SB1BB[C@H]2BBBBB[C@@H](B1)B2
InChI key
LJIJIIVFZSYPTF-NCGGTJAESA-N
assay
97%
form
solid
mp
181-185 °C
General description
m-Carborane-9-thiol is a carboranethiol that is used in the formation of self-assembled monolayers (SAMs) on a variety of surfaces.
Application
m-Carborane-9-thiol forms a SAM to tune the work function of gold and silver for potential applications in organic light emitting diodes (OLEDs). It can also be used in the synthesis of metal organic chalcogenides (MOC).
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Sterically controlled mechanochemistry under hydrostatic pressure
Yan H, et al.
Nature, 554(7693), 505-505 (2018)
Kai Kristiansen et al.
ACS nano, 8(10), 10870-10877 (2014-10-08)
Strong and particularly long ranged (>100 nm) interaction forces between apposing hydrophobic lipid monolayers are now well understood in terms of a partial turnover of mobile lipid patches, giving rise to a correlated long-range electrostatic attraction. Here we describe similarly
Interface control in organic electronics using mixed monolayers of carboranethiol isomers
Kim J, et al.
Nano Letters, 14(5), 2946-2951 (2014)
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