688533
(S)-2-[2-[Bis(2-tolyl)phosphino]phenyl]-4-tert-butyl-2-oxazoline
97%
Synonym(s):
(S)-2-[2-[Bis(2-tolyl)phosphino]phenyl]-4-tert-butyl-4,5-dihydro-oxazole
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About This Item
assay
97%
SMILES string
Cc1ccccc1P(c2ccccc2C)c3ccccc3C4=N[C@H](CO4)C(C)(C)C
InChI
1S/C27H30NOP/c1-19-12-6-9-15-22(19)30(23-16-10-7-13-20(23)2)24-17-11-8-14-21(24)26-28-25(18-29-26)27(3,4)5/h6-17,25H,18H2,1-5H3/t25-/m1/s1
InChI key
PWDWTBOBIGNWSX-RUZDIDTESA-N
form
solid
optical activity
[α]22/D −69.0, c = 1 in chloroform
mp
134-138 °C
functional group
ether, phosphine
storage temp.
−20°C
Quality Level
Related Categories
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Andreas Pfaltz's chiral ligand designs, like semicorrins, pioneered bisoxazolines for widespread catalytic asymmetric synthesis.
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