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Merck
CN

689017

N-[(2S)-2-Pyrrolidinylmethyl]-trifluoromethanesulfonamide

≥98.5% (T)

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About This Item

Empirical Formula (Hill Notation):
C6H11F3N2O2S
CAS Number:
782495-18-5
Molecular Weight:
232.22
NACRES:
NA.22
PubChem Substance ID:
329761211
UNSPSC Code:
12352005
MDL number:
MFCD11656045
Assay:
≥98.5% (T)
Form:
powder

Key Documents

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Product Name

N-[(2S)-2-Pyrrolidinylmethyl]-trifluoromethanesulfonamide, ≥98.5% (T)

InChI

1S/C6H11F3N2O2S/c7-6(8,9)14(12,13)11-4-5-2-1-3-10-5/h5,10-11H,1-4H2/t5-/m0/s1

SMILES string

FC(F)(F)S(=O)(=O)NC[C@@H]1CCCN1

InChI key

RIWFUAUXWIEOTK-YFKPBYRVSA-N

assay

≥98.5% (T)

form

powder

optical activity

[α]/D +13±1°, c = 1 in methanol

optical purity

ee: ≥98.5%

functional group

amine
fluoro

Quality Level

200

Related Categories

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
0000134699
0000134674
0000031527
0000005625
0000005626

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Direct, highly enantioselective pyrrolidine sulfonamide catalyzed Michael addition of aldehydes to nitrostyrenes.
Wei Wang et al.
Angewandte Chemie (International ed. in English), 44(9), 1369-1371 (2005-01-25)
Liansuo Zu et al.
Organic letters, 10(6), 1211-1214 (2008-02-15)
Fluorous (S) pyrrolidine sulfonamide serves as an efficient promoter for highly enantioselective aldol reactions of ketones and aldehydes with aromatic aldehydes on water. A notable feature of the organocatalyst is that it can be recovered from the reaction mixtures by
Liansuo Zu et al.
Organic letters, 8(14), 3077-3079 (2006-06-30)
[reaction: see text] A recycle and reusable fluorous (S)-pyrrolidine sulfonamide organocatalyst has been developed for promoting highly enantio- and diastereoselective Michael addition reactions of ketones and aldehydes with nitroolefins in water. The organocatalyst is conveniently recovered from the reaction mixtures

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