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693138

(S)-[(RuCl(BINAP))₂(μ-Cl)₃][NH₂Me₂]

Name: (S)-[(RuCl(BINAP))2(μ-Cl)3][NH2Me2]
Brand: ALDRICH

Synonym(s):

Dimethylammonium dichlorotri(μ-chloro)bis[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]diruthenate(II)

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About This Item

Linear Formula:

(CH₃)₂NH₂+[C₈₈H₆₄Cl₅P₄Ru₂]−

CAS Number:

199541-17-8

Molecular Weight:

1670.84

UNSPSC Code:

12352005

PubChem Substance ID:

329761565

MDL number:

MFCD09753033

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Properties

form

powder

functional group

amine, phosphine

storage temp.

2-8°C

SMILES string

Cl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.c3ccc(cc3)P(c4ccccc4)c5ccc6ccccc6c5-c7c(ccc8ccccc78)P(c9ccccc9)c%10ccccc%10.c%11ccc(cc%11)P(c%12ccccc%12)c%13ccc%14ccccc%14c%13-c%15c(ccc%16ccccc%15%16)P(c%17ccccc%17)c%18ccccc%18

InChI

1S/2C44H32P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-3-2;;;;;;;/h2*1-32H;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1

InChI key

FRRCROPKBKLCMQ-UHFFFAOYSA-M

Description

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

pictograms

GHS02

signalword

Warning

hcodes

H228

pcodes

P210

Hazard Classifications

Flam. Sol. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

MKBT3475V

MKAA4639

03325LH

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Global Trade Item Number

SKU	GTIN
693138-500MG	04061832625089
693138-100MG	04061832625072