693189
(S)-Ru(OAc)2(BINAP)
Synonym(s):
Diacetato[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]ruthenium(II)
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About This Item
Empirical Formula (Hill Notation):
C48H38O4P2Ru
CAS Number:
Molecular Weight:
841.83
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
MDL number:
form
powder
functional group
phosphine
storage temp.
2-8°C
InChI
1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);/q;;;+2/p-2
InChI key
NMLZYEWNUCRSRJ-UHFFFAOYSA-L
Application
Catalyst for:
- Synthesis of zaragozic acid D and formal syntheses of zaragozic acids A and C
- Enantioselective synthesis of the spirocyclic C-arylglycopyranoside (+)-papulacandin D via palladium-catalyzed, organosilanolate-based cross-coupling reaction and a Lewis-base catalyzed, enantioselective allylation reaction
- Asymmetric hydrogenation of 2-formyl-1-methylene-1,2,3,4-tetrahydroisoquinoline
- Asymmetric reduction of (nitro)(phenyl)propene
- Asymmetric synthesis of chiral d-lactones via hydrogenation
- Asymmetric hydrogenation of bis(diphenylphosphinoyl)butadiene
Legal Information
Sold in collaboration with Takasago for research purposes only.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 693189-500MG | 04061832625164 |
| 693189-100MG | 04061832625157 |