693537
R-MOP
≥94%
Synonym(s):
(R)-(+)-2-(Diphenylphosphino)-2′-methoxy-1,1′-binaphthyl
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About This Item
Empirical Formula (Hill Notation):
C33H25OP
CAS Number:
Molecular Weight:
468.52
UNSPSC Code:
12352005
PubChem Substance ID:
MDL number:
assay
≥94%
form
solid
optical activity
[α]20/D +94°, c = 0.5 in chloroform
SMILES string
COc1ccc2ccccc2c1-c3c(ccc4ccccc34)P(c5ccccc5)c6ccccc6
InChI
1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3
InChI key
KRWTWSSMURUMDE-UHFFFAOYSA-N
General description
R-MOP is a phosphine ligand with a bis-naphthalene backbone.
Application
Takasago Ligands and Complexes for Asymmetric Reactions
Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.
Ligand used in palladium-catalyzed asymmetric hydrosilylation of olefins, palladium-catalyzed reduction of allylic esters, rhodium-catalyzed asymmetric addition reactions, and asymmetric amination reactions catalyzed by copper(I) complexes.
Legal Information
Sold in collaboration with Takasago for research purposes only. US5231202
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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