693979
(1E,2E)-1,2-Bis(2,6-Diisopropylphenylimino)ethane
90%
Synonym(s):
N,N′-Bis(2,6-diisopropylphenyl)-1,4-diazabutadiene, N,N′-Bis(2,6-diisopropylphenyl)ethanediimine, Glyoxal bis(2,6-diisopropylanil)
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About This Item
Linear Formula:
(C3H7)2C6H3NCHCHNC6H3(C3H7)2
CAS Number:
Molecular Weight:
376.58
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
InChI
1S/C26H36N2/c1-17(2)21-11-9-12-22(18(3)4)25(21)27-15-16-28-26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3/b27-15+,28-16+
SMILES string
CC(C)c1cccc(C(C)C)c1\N=C\C=N\c2c(cccc2C(C)C)C(C)C
InChI key
JWVIIGXMTONOFR-DPCVLPDWSA-N
assay
90%
form
solid
reaction suitability
reagent type: ligand
mp
105-109 °C
Application
- Reactant in preparation of derived ruthenium olefin metathesis catalysts
- N-cyclic carbene ligand
Catalyst in:
- Palladium-catalyzed aerobic alc. oxidn. supported by a-diimine ligands
- Regioselective alkylation in presence of ruthenium-bisimine catalytic precursors
- N-arylation of aromatic amines
- Preparation of ruthenium nitrosyl alpha-diimine and iminoketone complexes as catalysts for transfer hydrogenation of ketones and atom transfer radical polymerization reactions
Storage Class
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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