695815
Bis(4-methylphenyl)chlorophosphine
96%
Synonym(s):
P,P-Bis(4-methylphenyl)-phosphinous chloride, Chlorodi-p-tolylphosphine
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About This Item
InChI key
BJBXRRHIBSXGLF-UHFFFAOYSA-N
SMILES string
Cc1ccc(cc1)P(Cl)c2ccc(C)cc2
InChI
1S/C14H14ClP/c1-11-3-7-13(8-4-11)16(15)14-9-5-12(2)6-10-14/h3-10H,1-2H3
assay
96%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
refractive index
n20/D 1.501
density
1.1 g/mL at 25 °C
functional group
phosphine
Quality Level
Application
- Palladium catalysts for C-C bond forming cross-coupling reactions
- Ligands for nickel(0)-catalyzed isomerization reactions
- Phosphinosulfonamide nickel complexes for oligomerization reactions
Reactant for:
- Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesis
- Phosphinylation reactions
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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