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Merck
CN

695904

1,3-Butadiene solution

15 wt. % in hexane

Synonym(s):

Bivinyl, Vinylethylene, alpha,gamma-Butadiene

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About This Item

Empirical Formula (Hill Notation):
C4H6
CAS Number:
106-99-0
Molecular Weight:
54.09
NACRES:
NA.22
PubChem Substance ID:
329761784
UNSPSC Code:
12352100
MDL number:
MFCD00008659
Form:
liquid

Key Documents

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form

liquid

concentration

15 wt. % in hexane

refractive index

n20/D 1.376

density

0.682 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

100

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Application

1,3-Butadiene can be used as a monomer to synthesize polybutadiene with one hydroxy end group and other silyl hydroxy-protecting end group, a precursor for two-step synthesis of hydroxyl-terminated polybutadiene (HTPB).

signalword

Danger

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-105.0 °F

flash_point_c

-76.11 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 1A - Flam. Liq. 2 - Muta. 1B - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

Regulatory Information

监管及禁止进口产品
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Certificates of Analysis (COA)

Lot/Batch Number
MKCX9860
MKCX9861
MKCV5485
MKCT3845
MKCN1917

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Synthesis of hydroxyl-terminated polybutadiene bearing pendant carboxyl groups by combination of anionic polymerization and blue light photocatalytic thiol-ene reaction and its pH-triggered self-assemble behavior.
Zhang W, et al.
Reactive and Functional Polymers, 127, 161-167 (2018)
Xin Min et al.
Royal Society open science, 5(5), 180156-180156 (2018-06-13)
A novel alkyl lithium-based initiator with relatively large steric hindrance, tert-butyldimethylsiloxydimethylpropyl lithium (TBDMSODPrLi), was designed and synthesized. By using TBDMSODPrLi, hydroxyl-terminated polybutadiene (HTPB) was prepared via anionic polymerization. The macromolecular structure of HTPB was characterized and verified by FTIR and
Masato Ohashi et al.
Journal of the American Chemical Society, 133(45), 18018-18021 (2011-10-19)
Pyridines, which comprise one of the most important classes of the six-membered heterocyclic compounds, are widely distributed in nature, and the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction of two alkynes and a nitrile is one of the most
Matthew S McCammant et al.
Journal of the American Chemical Society, 135(11), 4167-4170 (2013-03-12)
A palladium-catalyzed 1,4-addition across the commodity chemical 1,3-butadiene to afford skipped polyene products is reported. Through a palladium σ → π → σ allyl isomerization, two new carbon-carbon bonds are formed with high regioselectivity and trans stereoselectivity of the newly
Dewakar Sangaraju et al.
Analytical chemistry, 84(3), 1732-1739 (2012-01-10)
1,3-Butadiene (BD) is an important industrial chemical and a common environmental pollutant present in urban air. BD is classified as a human carcinogen based on epidemiological evidence for an increased incidence of leukemia in workers occupationally exposed to BD and
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