696196
1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene
97%, solid
Synonym(s):
Ipr, 1,3-Bis(2,6-diisopropylphenyl)imidazol-2-ylidene
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About This Item
Empirical Formula (Hill Notation):
C27H36N2
CAS Number:
Molecular Weight:
388.59
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22
Product Name
1,3-Bis(2,6-diisopropylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene, 97%
Assay
97%
form
solid
reaction suitability
reagent type: ligand
mp
213-217 °C
storage temp.
−20°C
SMILES string
CC(C)c1cccc(C(C)C)c1N2[C]N(C=C2)c3c(cccc3C(C)C)C(C)C
InChI
1S/C27H36N2/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8/h9-16,18-21H,1-8H3
InChI key
VYCIHDBIKGRENI-UHFFFAOYSA-N
Application
Ligand for Pd complexes for amination reaction of aryl halides; used as C-C bond formation reaction, e.g. Kumada-Tamao-Corriu reaction, Suzuki coupling, and Stille coupling.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Huang, J.; Nolan, S. P.
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