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Merck
CN

696617

Sigma-Aldrich

Palladium(II)[1,3-bis(diphenylphosphino)propane]-bis(benzonitrile)-bis-tetrafluoroborate

Synonym(s):

[Pd(dppp)(PhCN)2](BF4)2

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About This Item

Empirical Formula (Hill Notation):
C41H36B2F8N2P2Pd
CAS Number:
Molecular Weight:
898.71
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
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form

solid

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

SMILES string

[Pd++].F[B-](F)(F)F.F[B-](F)(F)F.N#Cc1ccccc1.N#Cc2ccccc2.C(CP(c3ccccc3)c4ccccc4)CP(c5ccccc5)c6ccccc6

InChI

1S/C27H26P2.2C7H5N.2BF4.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;2*8-6-7-4-2-1-3-5-7;2*2-1(3,4)5;/h1-12,14-21H,13,22-23H2;2*1-5H;;;/q;;;2*-1;+2

InChI key

VCESXCUPOICDRS-UHFFFAOYSA-N

Application

Catalyst for:
  • Synthesis of a photopatternable pentacene precursor
  • Diels-Alder reactions of dienes with aldehydes
Pd catalyst for Diels-Alder reactions.

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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