697230
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
powder
Synonym(s):
Pd(dppf)Cl2
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About This Item
Product Name
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II),
form
powder
Quality Segment
reaction suitability
core: palladium, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Buchwald-Hartwig Cross Coupling Reaction
mp
266-283 °C (lit.)
SMILES string
[Fe].Cl[Pd]Cl.[CH]1[CH][CH][C]([CH]1)P(c2ccccc2)c3ccccc3.[CH]4[CH][CH][C]([CH]4)P(c5ccccc5)c6ccccc6
InChI
1S/2C17H14P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-14H;2*1H;;/q;;;;;+2/p-2
InChI key
JCWIWBWXCVGEAN-UHFFFAOYSA-L
Application
- Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
- Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
- Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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