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697605

(S,S)-ANDEN-Phenyl Trost Ligand

Name: (<I>S</I>,<I>S</I>)-ANDEN-Phenyl Trost Ligand
Brand: ALDRICH

Synonym(s):

(+)-(11S,12S)Bis[2′-(diphenylphosphino)benzamido]-9,10-dihydro-9,10-ethanoanthracene, (11S,12S)-N,N′-(9,10-Dihydro-9,10-ethanoanthracene-11,12-diyl)bis[2-(diphenylphosphino)]benzamide

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About This Item

Empirical Formula (Hill Notation):

C₅₄H₄₂N₂O₂P₂

CAS Number:

138517-65-4

Molecular Weight:

812.87

UNSPSC Code:

12352002

PubChem Substance ID:

329761936

MDL number:

MFCD12546008

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Properties

optical activity

[α]22/D +111°, c = 1 in chloroform

mp

123-128 °C

SMILES string

O=C(N[C@@H]1[C@@H](NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)[C@H]5c6ccccc6[C@@H]1c7ccccc57)c8ccccc8P(c9ccccc9)c%10ccccc%10

InChI

1S/C54H42N2O2P2/c57-53(45-33-17-19-35-47(45)59(37-21-5-1-6-22-37)38-23-7-2-8-24-38)55-51-49-41-29-13-15-31-43(41)50(44-32-16-14-30-42(44)49)52(51)56-54(58)46-34-18-20-36-48(46)60(39-25-9-3-10-26-39)40-27-11-4-12-28-40/h1-36,49-52H,(H,55,57)(H,56,58)/t49-,50+,51-,52-/m0/s1

InChI key

BEKZNCOFLFMFHP-UYATXGGZSA-N

Description

Application

Asymmetric allylic alkylation ligand.

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only.

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number

96397LJ

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Trost, B.M. et al.

Journal of the American Chemical Society, 124, 11616-11616 (2004)

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Barry M. Trost et al.

Chemical reviews, 96(1), 395-422 (1996-02-01)