698474
Bis(4-methoxyphenyl)chlorophosphine
95%
Synonym(s):
P,P-Bis(4-methoxyphenyl)phosphinous chloride
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About This Item
InChI
1S/C14H14ClO2P/c1-16-11-3-7-13(8-4-11)18(15)14-9-5-12(17-2)6-10-14/h3-10H,1-2H3
SMILES string
COc1ccc(cc1)P(Cl)c2ccc(OC)cc2
InChI key
YTFQUBRFOJIJOZ-UHFFFAOYSA-N
assay
95%
form
solid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
mp
62-66 °C
functional group
phosphine
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Application
- Allylic substitution
- Intermolecular Pauson-Khand reaction of symmetrically substituted alkynes
- Hydrogenation
- Intramolecular α-arylation of aldehydes
Reactant for:
- Alcoholysis of phosphane-boranes
- Probing hemilabile sites of Bis(phosphine) monoxide ligands
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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