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Merck
CN

698687

F8BT

average Mn ≤25000

Synonym(s):

Poly(9,9-dioctylfluorene-alt-benzothiadiazole), Poly[(9,9-di-n-octylfluorenyl-2,7-diyl)-alt-(benzo[2,1,3]thiadiazol-4,8-diyl)]

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About This Item

Linear Formula:
(C35H42N2S)n
CAS Number:
210347-52-7
MDL number:
MFCD00002615
NACRES:
NA.23
UNSPSC Code:
12352103

Key Documents

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form

powder

mol wt

average Mn ≤25000

solubility

THF: soluble, chloroform: soluble

fluorescence

λex 447 nm; λem 530-560 nm in chloroform

Mw/Mn

<3

semiconductor properties

P-type (mobility=4×10−3 cm2/V·s)

Quality Level

100

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General description

F8BT is a fluorene copolymer that is used as a light-emitting polymer (LEP) with low energy of lowest unoccupied molecular orbital (LUMO), high electron mobility and luminance.

Application

F8BT can be used with poly(9,9-di-n-octylfluorenyl-2,7-diyl) (PTO) to map the effect of noise sources on photoconducting charge transports by evaluating the conductivity and noise source density (Nt). It may also form a nanocomposite with single walled carbon nanotube (SWCNT) with excellent electric properties and high Seebeck coefficient, for potential application in the development of photovoltaic power and biomass energy. Organic light emitting diode (OLED) devices can be fabricated by depositing a blend of F8 and F8BT on PEDOT:PSS films.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF8283V
WXBF7375V
WXBF6613V
WXBF4753V
MKCQ9539

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Morphology-dependent trap formation in bulk heterojunction photodiodes
Shao G, et al.
The Journal of Physical Chemistry B, 117(16), 4654-4660 (2013)
Surface, interface and electronic properties of F8: F8BT polymeric thin films used for organic light-emitting diode applications
Borges BG, et al.
Polymer International, 67(6), 691-699 (2018)
Efficient polymer light-emitting diode using air-stable metal oxides as electrodes
Bolink HJ, et al.
Advanced Materials, 21(1), 79-82 (2009)
Enhanced figure of merit of poly (9, 9-di-n-octylfluorene-alt-benzothiadiazole) and SWCNT thermoelectric composites by doping with FeCl3
Zhou X, et al.
Journal of Applied Polymer Science, 16(3), 47011-47011 (2018)
Lay-Lay Chua et al.
Nature, 434(7030), 194-199 (2005-03-11)
Organic semiconductors have been the subject of active research for over a decade now, with applications emerging in light-emitting displays and printable electronic circuits. One characteristic feature of these materials is the strong trapping of electrons but not holes: organic
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