698709
Allylboronic acid MIDA ester
Synonym(s):
2-Allyl-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione
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About This Item
Empirical Formula (Hill Notation):
C8H12BNO4
Molecular Weight:
197.00
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
InChI
1S/C8H12BNO4/c1-3-4-9-13-7(11)5-10(2)6-8(12)14-9/h3H,1,4-6H2,2H3
SMILES string
CN1CC(=O)OB(CC=C)OC(=O)C1
InChI key
RKMASTMFHKLQNL-UHFFFAOYSA-N
form
solid
Other Notes
May contain up to 10 wt. % dimethyl sulfoxide.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Sabin Llona-Minguez et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(20), 7394-7398 (2015-03-27)
A two-step synthesis of structurally diverse pyrrole-containing bicyclic systems is reported. ortho-Nitro-haloarenes coupled with vinylic N-methyliminodiacetic acid (MIDA) boronates generate ortho-vinyl-nitroarenes, which undergo a "metal-free" nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide
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