699918
(R)-N-[(1R,2R)-2-(3-(3,5-双(三氟甲基)苯基)脲基)环己基]-叔丁基亚磺酰胺
96%
别名:
[S(R)]-N-[(1R,2R)-2-[[[[3,5-Bis(trifluoromethyl)phenyl]amino]carbonyl]amino]cyclohexyl]-2-methyl-2-propanesulfinamide
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关于此项目
经验公式（希尔记法）:
C19H25F6N3O2S
化学文摘社编号:
分子量:
473.48
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352002
MDL number:
assay
96%
form
solid
mp
173-181 °C
functional group
amine, fluoro
SMILES string
CC(C)(C)S(=O)N[C@@H]1CCCC[C@H]1NC(=O)Nc2cc(cc(c2)C(F)(F)F)C(F)(F)F
InChI
1S/C19H25F6N3O2S/c1-17(2,3)31(30)28-15-7-5-4-6-14(15)27-16(29)26-13-9-11(18(20,21)22)8-12(10-13)19(23,24)25/h8-10,14-15,28H,4-7H2,1-3H3,(H2,26,27,29)/t14-,15-,31-/m1/s1
InChI key
WMIJNZVQFOPOBW-ZHANGXNJSA-N
Application
(R)-N-[(1R,2R)-2-(3-(3,5-Bis(trifluoromethyl)phenyl)ureido)cyclohexyl]-tert-butyl-sulfinamide is a sulfinamide-urea based chiral catalyst that can be used to synthesize:
- Enantioselective homoallylic amines by asymmetric allylation of acylhydrazones with allylindium reagents.
- Tetrahydroquinolines via an asymmetric Povarov reaction.
- 2-aryl-substituted cycloalkanones by enantioselective protonation of corresponding trimethylsilyl enol ethers.
hcodes
Hazard Classifications
Aquatic Chronic 4
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)