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700045

(2-Butenyl)chloropalladium dimer

≥97%, powder

Synonym(s):

Bis[(1,2,3-η)-2-buten-1-yl]di-μ-chlorodi-palladiumdi-π-crotylpalladium chloride, Di-π-Crotylpalladium chloride, Di-2-butenyldipalladium dichloride, Dichlorobis(1-methylallyl)dipalladium

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About This Item

Empirical Formula (Hill Notation):
C8H14Cl2Pd2
CAS Number:
12081-22-0
Molecular Weight:
393.94
UNSPSC Code:
12161600
PubChem Substance ID:
329762176
NACRES:
NA.22
MDL number:
MFCD01074457
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Product Name

(2-Butenyl)chloropalladium dimer, ≥97%

Quality Level

100

assay

≥97%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

133-140 °C

SMILES string

C\C=C\C[Pd]Cl.C\C=C\C[Pd]Cl

InChI

1S/2C4H7.2ClH.2Pd/c2*1-3-4-2;;;;/h2*3-4H,1H2,2H3;2*1H;;/q;;;;2*+1/p-2/b2*4-3+;;;;

InChI key

NTFUUQYNUUTALG-HYTOEPEZSA-L

Application

Catalyst for:
  • Enantioselective elimination of palladium hydride
  • Non-covalent anchoring of catalysts to silica supports
  • Allylations of cyanoacetates
  • Enantioselective nucleophilic substitutions

Reactant for:
  • Allylic alkylation reactions
  • Preparation of phosphane-functionalized carbosilane dendrimers

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCZ4360
MKCW7631
MKCT2921
MKCR4955
MKCQ7780

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Global Trade Item Number

SKUGTIN
700045-1G04061826734094
700045-250MG04061833483756