701106
2-Benzofuranylboronic acid MIDA ester
97%
Synonym(s):
2-(Benzofuran-2-yl)-6-methyl-1,3,6,2-dioxazaborocane-4,8-dione, 2-Benzofuranboronic acid MIDA ester
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About This Item
Empirical Formula (Hill Notation):
C13H12BNO5
CAS Number:
Molecular Weight:
273.05
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
Assay
97%
form
powder
mp
198-202 °C
SMILES string
CN1CC(=O)OB(OC(=O)C1)c2cc3ccccc3o2
InChI
1S/C13H12BNO5/c1-15-7-12(16)19-14(20-13(17)8-15)11-6-9-4-2-3-5-10(9)18-11/h2-6H,7-8H2,1H3
InChI key
ASPDKYQZQMDSKZ-UHFFFAOYSA-N
Storage Class Code
13 - Non Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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David M Knapp et al.
Journal of the American Chemical Society, 131(20), 6961-6963 (2009-05-02)
Many boronic acids, including 2-heterocyclic, vinyl, and cyclopropyl derivatives, are inherently unstable, which can limit their benchtop storage and/or efficient cross-coupling. We herein report the first general solution to this problem: in situ slow release of unstable boronic acids from
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