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About This Item
Empirical Formula (Hill Notation):
C18H15AuClO3P
Molecular Weight:
542.70
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
assay
97%
reaction suitability
reagent type: catalyst
core: gold
mp
97-102 °C
SMILES string
Cl[Au].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3
InChI
1S/C18H15O3P.Au.ClH/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChI key
DADNGSZZNVQSMJ-UHFFFAOYSA-M
Application
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Regulatory Information
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Michael A Tarselli et al.
The Journal of organic chemistry, 73(6), 2439-2441 (2008-02-19)
Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room temperature.
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