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Merck
CN

701505

Chloro(triphenylphosphite)gold

97%

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About This Item

Empirical Formula (Hill Notation):
C18H15AuClO3P
Molecular Weight:
542.70
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
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assay

97%

reaction suitability

reagent type: catalyst
core: gold

mp

97-102 °C

SMILES string

Cl[Au].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3

InChI

1S/C18H15O3P.Au.ClH/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1

InChI key

DADNGSZZNVQSMJ-UHFFFAOYSA-M

Application

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Information

新产品

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Michael A Tarselli et al.
The Journal of organic chemistry, 73(6), 2439-2441 (2008-02-19)
Gold(I) complexes react with 4-allenyl arenes in an exo fashion to furnish vinyl-substituted benzocycles. Phosphite gold(I) monocations were found to be optimal, and the catalyst was tolerant of ethers, esters, and pyrroles. Reactions proceeded in unpurified solvent at room temperature.

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