701742
Copper(I) chloride - bis(lithium chloride) complex
1 M in THF, liquid
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About This Item
Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Product Name
Copper(I) chloride - bis(lithium chloride) complex, 1 M in THF
form
liquid
reaction suitability
core: copper
reagent type: catalyst
concentration
1 M in THF
refractive index
n20/D 1.442
density
1.015 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.Cl[Cu]
InChI
1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3
InChI key
QJRAZNXUNZEAQH-UHFFFAOYSA-K
Related Categories
Application
Solution used in Cu(I) transmetallation for amination reaction
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
62.6 °F
Flash Point(C)
17.0 °C
Regulatory Information
监管及禁止进口产品
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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)
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