701742
Copper(I) chloride - bis(lithium chloride) complex
1 M in THF, liquid
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About This Item
Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
Product Name
Copper(I) chloride - bis(lithium chloride) complex, 1 M in THF
SMILES string
[Li]Cl.[Li]Cl.Cl[Cu]
InChI
1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3
InChI key
QJRAZNXUNZEAQH-UHFFFAOYSA-K
form
liquid
reaction suitability
core: copper, reagent type: catalyst
concentration
1 M in THF
refractive index
n20/D 1.442
density
1.015 g/mL at 25 °C
Quality Level
Related Categories
Application
Solution used in Cu(I) transmetallation for amination reaction
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
62.6 °F
flash_point_c
17.0 °C
Regulatory Information
监管及禁止进口产品
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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)
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