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701742

Copper(I) chloride - bis(lithium chloride) complex

1 M in THF, liquid

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About This Item

Linear Formula:
CuCl · 2LiCl
Molecular Weight:
183.79
UNSPSC Code:
12161600
PubChem Substance ID:
329762317
NACRES:
NA.22
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Product Name

Copper(I) chloride - bis(lithium chloride) complex, 1 M in THF

form

liquid

Quality Level

100

reaction suitability

core: copper, reagent type: catalyst

concentration

1 M in THF

refractive index

n20/D 1.442

density

1.015 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.Cl[Cu]

InChI

1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3

InChI key

QJRAZNXUNZEAQH-UHFFFAOYSA-K

Application

Solution used in Cu(I) transmetallation for amination reaction

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

62.6 °F

flash_point_c

17.0 °C

Regulatory Information

监管及禁止进口产品

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Certificates of Analysis (COA)

Lot/Batch Number
SHBL2905
SHBJ8231
SHBG2790V
SHBC3552
07928EJ

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Kienle, M. et al.
Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Vicente Del Amo et al.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)

Global Trade Item Number

SKUGTIN
701742-50ML04061838120731