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Merck
CN

702471

PTAA

greener alternative

a poly(triaryl amine) semiconductor

Synonym(s):

Poly(triaryl amine), Poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine], Poly[[(2,4,6-trimethylphenyl)imino][1,1′-biphenyl]-4,4′-diyl]

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About This Item

Linear Formula:
[C6H4N(C6H2(CH3)3)C6H4]n
CAS Number:
MDL number:
NACRES:
NA.23
UNSPSC Code:
32111503
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form

solid

mol wt

average Mn 7,000-10,000 (GPC)

storage condition

(If stored in the absence of light, there will be no change over at least 24 months)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>400 °C

solubility

soluble (Soluble in THF, toluene, chloroform, chlorobenzene, and dichlorobenzene.)

Mw/Mn

2‑2.2

application(s)

battery manufacturing
semiconductor

greener alternative category

semiconductor properties

P-type (mobility=10−3 - 10−2 cm2/V·s)

General description

PTAA, poly(triaryl amine), semiconductor is an organic p-type semiconductor with hole mobilities of 10−3 up to 10−2 cm2 V−1 s−1 which results in a high carrier mobility. It is a stable glassy polymer and has good ionization potential for thick film diodes.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Application

PTAA can be coated as a substrate material which is used for the transportation of hole in the fabrication of many devices like perovskite solar cells, polymeric light emitting diodes and organic field effect transistors.


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



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Articles

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Related Content

Instructions


Solvent engineering for high-performance inorganic-organic hybrid perovskite solar cells.
Jeon NJ, et al.
Nature Materials, 13(9), 897-897 (2014)
M.L. Chabinyc, L.H. Jimison, J. Rivnay, A. Salleo
Mrs Bulletin, 33, 683-683 (2008)
Characterization of thick film poly (triarylamine) semiconductor diodes for direct x-ray detection.
Intaniwet A, et al.
Journal of Applied Physics, 106(6), 064513-064513 (2009)



Global Trade Item Number

SKUGTIN
702471-1G04061832820972
702471-100MG04061832820958