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Merck
CN

704067

ε-Caprolactone

97%

Synonym(s):

2-Oxepanone, 6-Caprolactone monomer, 6-Hexanolactone

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About This Item

Empirical Formula (Hill Notation):
C6H10O2
CAS Number:
Molecular Weight:
114.14
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
207-938-1
Beilstein/REAXYS Number:
106919
MDL number:
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vapor density

3.9 (vs air)

Quality Level

vapor pressure

0.01 mmHg ( 20 °C)

assay

97%

form

liquid

refractive index

n20/D 1.463 (lit.)

bp

97-98 °C/15 mmHg (lit.)

density

1.03 g/mL at 25 °C (lit.)

SMILES string

O=C1CCCCCO1

InChI

1S/C6H10O2/c7-6-4-2-1-3-5-8-6/h1-5H2

InChI key

PAPBSGBWRJIAAV-UHFFFAOYSA-N

General description

ε-caprolactone is a cyclic ester. Ring opening polymerization of ε-caprolactone initiated by, tributylin n butoxide, ethyl magnesium bromide, or samarium acetate or heteropolyacid, leads to the formation of poly caprolactone (PCL).

Application

ε-caprolactone is popularly used in the preparation of poly caprolactone (PCL).


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter



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Related Content

Explore the design of cleavable comonomers for advanced deconstructable polymers and practical strategies to overcome synthesis challenges and their applications.


Yanzhu Guo et al.
Carbohydrate polymers, 92(1), 77-83 (2012-12-12)
Self-associating cellulose-graft-poly(ɛ-caprolactone) (cellulose-g-PCL) copolymers were successfully synthesized via homogeneous ring-opening polymerization (ROP) of ɛ-CL onto softwood dissolved pulp substrate in ionic liquid 1-N-butyl-3-methylimidazolium chloride ([Bmim]Cl). An organic catalyst N,N-dimethylamino-4-pyridine (DMAP) was compared with the traditional metal-based catalyst (Sn(Oct)(2)) as the
Leonardus Kresna Widjaja et al.
Journal of the mechanical behavior of biomedical materials, 6, 80-88 (2012-02-04)
A series of triblock copolymers comprising end block of PLLA modified with PCL, and random copolymer of PCL and PTMC as soft segment were synthesized. DSC data show that PCL disrupted the crystallinity of PLLA, making the hard block to
Eliza Li Shan Fong et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(16), 6500-6505 (2013-04-12)
The pronounced biological influence of the tumor microenvironment on cancer progression and metastasis has gained increased recognition over the past decade, yet most preclinical antineoplastic drug testing is still reliant on conventional 2D cell culture systems. Although monolayer cultures recapitulate



Global Trade Item Number

SKUGTIN
704067-100G04061838254207
704067-500G04061838254214