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Merck
CN

704083

Trifluoromethanesulfonic anhydride solution

1 M in methylene chloride

Synonym(s):

Perfluoromethanesulfonic anhydride solution, Triflic anhydride solution

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About This Item

Empirical Formula (Hill Notation):
C2F6O5S2
CAS Number:
Molecular Weight:
282.14
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
MDL number:
Form:
liquid
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form

liquid

Quality Segment

concentration

1 M in methylene chloride

refractive index

n20/D 1.402

density

1.359 g/mL at 25 °C

functional group

fluoro, triflate

storage temp.

2-8°C

SMILES string

FC(F)(F)C(=O)OC(=O)C(F)(F)F

InChI

1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8

InChI key

WJKHJLXJJJATHN-UHFFFAOYSA-N

Application

Trifluoromethanesulfonic anhydride solution is generally used to convert hydroxyl groups to triflic esters. It can be used to prepare triflic azide for azido amino acid synthesis.
Catalyst for synthesis of Bacteroides fragilis zwitterionic polysaccharide Ai tetrasaccharide repeating unit via glycosylation

Reagent for stereoselective synthesis of mennosazide methyl uronate donors

Activator for direct glycosylation with anomeric hydroxy sugars


Signal Word

Danger

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Storage Class

5.1B - Oxidizing hazardous materials

Flash Point (°F)

Not applicable

Flash Point (°C)

Not applicable

supp_hazards



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