704091
Tributyltin hydride solution
1 M in cyclohexane
Synonym(s):
Tributylstannane, Tributylstannyl hydride
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About This Item
Empirical Formula (Hill Notation):
C12H28Sn
CAS Number:
Molecular Weight:
291.06
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
Form:
liquid
InChI
1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;
SMILES string
CCCC[SnH](CCCC)CCCC
InChI key
DBGVGMSCBYYSLD-UHFFFAOYSA-N
form
liquid
reaction suitability
reagent type: reductant
concentration
1 M in cyclohexane
refractive index
n20/D 1.438
density
0.895 g/mL at 25 °C
Application
Reactant or reagent for:
- Alkyne hydrostannations
- Intramolcular cyclization for the synthesis of zoanthamine alkaloids
- Stereoselective C-glycosylation of pyranosides using Heck allylation
- Synthesis of phenylbutenoid dimers for use in treating diseases
- Preparation of N-acyl derivatives of ecteinascidin 770
- Syntehsis of cyclonucleosides using black light induced radical cyclization
flash_point_f
5.0 °F
flash_point_c
-15 °C
Regulatory Information
监管及禁止进口产品
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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Ang Yu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 158-162 (2013-01-15)
Tributyltin (TBT) is a ubiquitous marine contaminant due to its extensive use as a biocide, fungicide and antifouling agent. However, the neurotoxic effect of TBT has not been extensively studied, especially in marine fish. This study was conducted to investigate
Chrystelle Bancon-Montigny et al.
Environmental technology, 33(19-21), 2229-2233 (2013-02-12)
Micro-pollutant fluxes distribution throughout the physical separation and biological units of wastewater treatment plants (WWTPs) are very dependent ofsorption phenomena. The understanding and the control of the sorption stage is thus essential for the optimization of micro-pollutant removal in WWTPs
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