705098
(S,S)-2-Allyl-1,3-bis-(4-bromobenzyl)-2-chlorooctahydro-2-1H-1,3,2-benzodiazasilole
95%
Synonym(s):
(S,S)-1,3-Bis-[(4-bromophenyl)methyl]-2-chlorooctahydro-2-(2-propenyl)-1H-1,3,2-benzodiazasilole
Sign In to View Organizational & Contract Pricing.
Select a Size
About This Item
Empirical Formula (Hill Notation):
C23H27Br2ClN2Si
Molecular Weight:
554.82
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
InChI
1S/C23H27Br2ClN2Si/c1-2-15-29(26)27(16-18-7-11-20(24)12-8-18)22-5-3-4-6-23(22)28(29)17-19-9-13-21(25)14-10-19/h2,7-14,22-23H,1,3-6,15-17H2/t22-,23-/m0/s1
SMILES string
Cl[Si]1(CC=C)N(Cc2ccc(Br)cc2)[C@H]3CCCC[C@@H]3N1Cc4ccc(Br)cc4
InChI key
JTYONYYNZDUUGN-GOTSBHOMSA-N
assay
95%
form
solid
optical activity
[α]22/D +54°, c = 1 in chloroform
mp
94-99 °C
storage temp.
2-8°C
Application
An operationally simple regioselective and enantioselective allylation of beta-diketones to provide tertiary carbinols
Legal Information
U.S. Patent No. 7,534,905
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Wesley A Chalifoux et al.
Nature, 487(7405), 86-89 (2012-07-06)
The enantioselective allylation of ketones is a problem of fundamental importance in asymmetric reaction design, especially given that only a very small number of methods can generate tertiary carbinols. Despite the vast amount of attention that synthetic chemists have given
Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.
Contact Technical Service