706000
Fluorotris(triphenylphosphine)copper(I)
95% (by HMR)
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About This Item
Empirical Formula (Hill Notation):
C54H45CuFP3
CAS Number:
Molecular Weight:
869.40
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/3C18H15P.Cu.FH/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;;1H/q;;;+1;/p-1
SMILES string
F[Cu].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
InChI key
OKJARODAQSGFQE-UHFFFAOYSA-M
assay
95% (by HMR)
form
solid
reaction suitability
reagent type: catalyst
core: copper
mp
144-157 °C
General description
Product may contain up to 9 wt. % ethanol as a complex.
Application
Complex used in asymmetric aldol reaction
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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Kounosuke Oisaki et al.
Journal of the American Chemical Society, 128(22), 7164-7165 (2006-06-01)
An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique accelerative effect of
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