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Merck
CN

706000

Fluorotris(triphenylphosphine)copper(I)

95% (by HMR)

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About This Item

Empirical Formula (Hill Notation):
C54H45CuFP3
CAS Number:
25753-74-6
Molecular Weight:
869.40
MDL number:
MFCD12546045
UNSPSC Code:
12352300
PubChem Substance ID:
329762604

Key Documents

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Assay

95% (by HMR)

form

solid

reaction suitability

reagent type: catalyst
core: copper

mp

144-157 °C

SMILES string

F[Cu].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9

InChI

1S/3C18H15P.Cu.FH/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h3*1-15H;;1H/q;;;+1;/p-1

InChI key

OKJARODAQSGFQE-UHFFFAOYSA-M

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General description

Product may contain up to 9 wt. % ethanol as a complex.

Application

Complex used in asymmetric aldol reaction

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
77196PJ

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Kounosuke Oisaki et al.
Journal of the American Chemical Society, 128(22), 7164-7165 (2006-06-01)
An enantioselective aldol reaction between ketones and ketene silyl acetals is described using CuF-chiral phosphine as a catalyst. The key for high enantioselectivity was the development of a novel ligand derived from Taniaphos combined with the unique accelerative effect of

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