706515
Copper hydride (CuH) solution
in toluene, liquid
Synonym(s):
"Hot" Stryker′s Reagent, (BDP)Cu(H), Copper monohydride, Cuprous hydride
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About This Item
Linear Formula:
CuH
CAS Number:
Molecular Weight:
64.55
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Copper hydride (CuH) solution, in toluene
SMILES string
[CuH]
InChI
1S/Cu.H
InChI key
JJFLDSOAQUJVBF-UHFFFAOYSA-N
form
liquid
reaction suitability
core: copper, reagent type: catalyst
concentration
in toluene
storage temp.
−20°C
Application
Reagent for stereoselective synthesis of exocyclic tetra substituted enol ethers and olefins
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 2 - STOT SE 3
target_organs
Central nervous system
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
42.8 °F
flash_point_c
6 °C
Regulatory Information
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Benjamin A Baker et al.
Organic letters, 10(2), 289-292 (2007-12-21)
A ligand-modified, economical version of Stryker's reagent (SR) has been developed based on a bidentate, achiral bis-phosphine. Generated in situ, "(BDP)CuH" smoothly effects conjugate reductions of a variety of unsaturated substrates, including those that are normally unreactive toward SR. Substrate-to-ligand
Niklas O Thiel et al.
Organic & biomolecular chemistry, 14(45), 10660-10666 (2016-10-27)
An air-stable and preactivated copper(i) hydroxide/N-heteroyclic carbene (NHC) complex for alkyne semihydrogenations is reported. Next to an enhanced practicability of the process, the resulting alkenes are obtained with high Z-selectivities and no overreduction to the corresponding alkanes.
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