706671
(4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1-oxa-3-aza-2-silacyclopentane
Synonym(s):
(1S,2S)-pseudoephedrine allylchlorosilane, (4S,5S)-2-Allyl-2-chloro-3,4-dimethyl-5-phenyl-1,3,2-oxazasilolidine, (4S,5S)-2-Chloro-3,4-dimethyl-5-phenyl-2-(2-propenyl)-1-oxa-3-aza-2-silacyclopentane
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About This Item
InChI
1S/C13H18ClNOSi/c1-4-10-17(14)15(3)11(2)13(16-17)12-8-6-5-7-9-12/h4-9,11,13H,1,10H2,2-3H3/t11-,13+,17?/m0/s1
SMILES string
C[C@H]1[C@@H](O[Si](Cl)(CC=C)N1C)c2ccccc2
InChI key
XHCRAANIMMYPDV-APBZJUGRSA-N
form
liquid
optical activity
[α]20/D 72.5°, c = 0.6 in ethanol (200 proof)
refractive index
n20/D 1.517
bp
120 °C/5 mmHg
density
1.095 g/mL at 25 °C
General description
Application
- Practical, enantioselective allylation of acylhydrazones
- Enantioselective allylation of ketimines: synthesis of tertiary carbinamines
Legal Information
signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
target_organs
Respiratory system
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
100.4 °F
flash_point_c
38 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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