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Merck
CN

707031

6-Methoxy-2-(tributylstannyl)pyrimidine

95%

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About This Item

Empirical Formula (Hill Notation):
C17H32N2OSn
CAS Number:
850501-35-8
Molecular Weight:
399.16
NACRES:
NA.22
PubChem Substance ID:
329762684
UNSPSC Code:
12352103
MDL number:
MFCD15143643
Assay:
95%
Form:
liquid

Key Documents

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InChI

1S/C5H5N2O.3C4H9.Sn/c1-8-5-2-3-6-4-7-5;3*1-3-4-2;/h2-3H,1H3;3*1,3-4H2,2H3;

SMILES string

CCCC[Sn](CCCC)(CCCC)c1nccc(OC)n1

InChI key

HQUSEOSQVFRYQV-UHFFFAOYSA-N

assay

95%

form

liquid

refractive index

n20/D 1.507

bp

293 °C

density

1.164 g/mL at 25 °C

Quality Level

100

Related Categories

General description

6-Methoxy-2-(tributylstannyl)pyrimidine is an organotin compound used in Stille coupling reaction.

Application

6-Methoxy-2-(tributylstannyl)pyrimidine can be used as a reactant for the preparation of substituted pyrimidinone compounds via a Stille coupling reaction with aryl bromides. It can be also employed for the preparation of 4-methoxy-2-phenylpyrimidine by reacting with iodobenzene using Pd as a catalyst.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
MKBB3696V
MKBC2890
MKBB3696

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Synthesis of new polyaza heterocycles. Part 42: Diazines
Darabantu M, et al.
Tetrahedron, 61(11), 2897-2905 (2005)
Synthesis of Mono-and Diaza-`Pyridones? via Stille Coupling of Alkoxystannanes
Smith CL, et al.
Synlett, 25(13), 1904-1908 (2014)

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