710024
1-Phenylvinylboronic acid MIDA ester
97%
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About This Item
Empirical Formula (Hill Notation):
C13H14BNO4
CAS Number:
Molecular Weight:
259.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
InChI
1S/C13H14BNO4/c1-10(11-6-4-3-5-7-11)14-18-12(16)8-15(2)9-13(17)19-14/h3-7H,1,8-9H2,2H3
SMILES string
CN1CC(=O)OB(OC(=O)C1)C(=C)c2ccccc2
InChI key
LDAWJVVAQPYNSX-UHFFFAOYSA-N
assay
97%
form
solid
mp
186-190 °C
functional group
phenyl
Application
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Sabin Llona-Minguez et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(20), 7394-7398 (2015-03-27)
A two-step synthesis of structurally diverse pyrrole-containing bicyclic systems is reported. ortho-Nitro-haloarenes coupled with vinylic N-methyliminodiacetic acid (MIDA) boronates generate ortho-vinyl-nitroarenes, which undergo a "metal-free" nitrene insertion, resulting in a new pyrrole ring. This novel synthetic approach has a wide
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