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Merck
CN

710369

Bis(2-furyl)phosphine chloride

85%

Synonym(s):

Di-2-furanylphosphinous chloride

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About This Item

Empirical Formula (Hill Notation):
C8H6ClO2P
CAS Number:
181257-35-2
Molecular Weight:
200.56
UNSPSC Code:
12352005
PubChem Substance ID:
329762918
MDL number:
MFCD01630851

Key Documents

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InChI

1S/C8H6ClO2P/c9-12(7-3-1-5-10-7)8-4-2-6-11-8/h1-6H

SMILES string

ClP(c1ccco1)c2ccco2

InChI key

IYEUYNXDXNWPJI-UHFFFAOYSA-N

assay

85%

form

liquid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

refractive index

n20/D 1.593

density

1.287 g/mL at 25 °C

functional group

phosphine

Application

Reactant for synthesis of:
  • Centrostereogenic 1,3-bidentate ferrocenyldiphosphane ligands
  • Ferrocene-based chiral diphosphine
  • Phosphine containing amino acids

Reactant for:
  • α-Arylation of aldehydes
  • Stereoselective [2,3] sigmatropic rearrangement of acyclic allylic phosphinites
  • Hydrophosphination of functionalized alkenes

pictograms

FlameCorrosion
GHS02,GHS05

signalword

Danger

hcodes

H261,H314

Hazard Classifications

Skin Corr. 1B - Water-react 2

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBM8258
SHBL1964
SHBK8524
SHBJ5982
SHBG8082V

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P M Ferreira et al.
Scientific reports, 10(1), 18061-18061 (2020-10-24)
Platelet-derived extracellular vesicles (PDEVs) are the most abundant amongst all types of EVs in the circulation. However, the mechanisms leading to PDEVs release, their role in coagulation and phenotypic composition are poorly understood. PDEVs from washed platelets were generated using

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