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Merck
CN

710504

Bis(4-methoxyphenyl)phosphine

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About This Item

Empirical Formula (Hill Notation):
C14H15O2P
CAS Number:
Molecular Weight:
246.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352112
MDL number:
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InChI

1S/C14H15O2P/c1-15-11-3-7-13(8-4-11)17-14-9-5-12(16-2)6-10-14/h3-10,17H,1-2H3

SMILES string

COc1ccc(Pc2ccc(OC)cc2)cc1

InChI key

FWKICRREDMVWRF-UHFFFAOYSA-N

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst, reagent type: ligand

mp

36-40 °C

functional group

phosphine

Application

Reactant for:
  • Enantioselective Ir-catalyzed hydrogenation
  • Palladium-catalyzed asymmetric additions
  • Alkali-metal-catalyzed addition reactions
  • Preparation of different DIOP-type ligands for uses in Rh-catalyzed asymmetric hydrogenation

pictograms

FlameExclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

>230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup


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