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710857

Iron(III) chloride solution

Name: Iron(III) chloride solution
Brand: ALDRICH

0.2 M in 2-methyltetrahydrofuran, solution

Synonym(s):

Ferric chloride solution

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About This Item

Linear Formula:

FeCl₃

CAS Number:

7705-08-0

Molecular Weight:

162.20

UNSPSC Code:

12161600

PubChem Substance ID:

329763016

NACRES:

NA.22

MDL number:

MFCD00011005

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Properties

Product Name

Iron(III) chloride solution, 0.2 M in 2-methyltetrahydrofuran

form

solution

Quality Level

100

reaction suitability

core: iron, reagent type: catalyst

greener alternative product characteristics

Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

concentration

0.2 M in 2-methyltetrahydrofuran

refractive index

n20/D 1.414

density

0.868 g/mL at 25 °C

greener alternative category

, Aligned

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

Description

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. FeCl₃ is used in many biomass conversion processes because of its unique properties such as nontoxicity, low-cost, abundance, and high selectivity. Here, this product is 0.2 M in 2-methyltetrahydrofuran and thus aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks", and has been enhanced for catalytic efficiency. Click here for more information.

Application

Iron(III) chloride in greener solvent, 2-methyltetrahydrofuran (2-MeTHF) can be used:

As a mild oxidant for phenolic coupling reaction.
In dimerizing aryllithiumsand ketone enolates.
As a mild Lewis acid catalyst to catalyzes ene reactions.
In Nazarov cyclizations, Michael additions, and acetonation reactions.

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

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pictograms

GHS02,GHS05,GHS07

signalword

Danger

hcodes

H225,H290,H302,H315,H318

pcodes

P210 - P233 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

14.0 °F - closed cup

flash_point_c

-10.0 °C - closed cup

Regulatory Information

危险化学品

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Certificates of Analysis (COA)

Lot/Batch Number

0000464917

0000429610

0000333887

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Clinical application of immunomagnetic reduction for quantitative measurement of insulin-like growth factor binding protein-1 in the prediction of pregnant women with preterm premature rupture of membranes.

Chen-Yu Chen et al.

Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)

Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was

Iron(III) chloride in oxidative C-C coupling reactions.

Abdelwareth A O Sarhan et al.

Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)

In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access

Iron halide-mediated regio- and stereoselective halosulfonylation of terminal alkynes with sulfonylhydrazides: synthesis of (E)-β-chloro and bromo vinylsulfones.

Xiaoqing Li et al.

The Journal of organic chemistry, 78(18), 9499-9504 (2013-08-28)

Halosulfonylation of terminal alkynes was achieved with sulfonylhydrazides as the sulfonyl precursor and inexpensive iron halide as halide source in the presence of TBHP, allowing the regio- and stereoselective generation of (E)-β-chloro and bromo vinylsulfones.

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Global Trade Item Number

SKU	GTIN
710857-50ML	04061832843605