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714852

1,8-Diazabicyclo[5.4.0]undec-7-ene solution

1 M in THF

Synonym(s):

DBU solution

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About This Item

Empirical Formula (Hill Notation):
C9H16N2
Molecular Weight:
152.24
UNSPSC Code:
12352302
PubChem Substance ID:
329763320
MDL number:
MFCD00006930
Concentration:
1 M in THF
Form:
liquid
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form

liquid

concentration

1 M in THF

refractive index

n20/D 1.425

density

0.899 g/mL at 25 °C

SMILES string

C1CCN2CCCN=C2CC1

InChI

1S/C9H16N2/c1-2-5-9-10-6-4-8-11(9)7-3-1/h1-8H2

InChI key

GQHTUMJGOHRCHB-UHFFFAOYSA-N

signalword

Danger

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

-0.0 °F

flash_point_c

-17.8 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

Regulatory Information

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Certificates of Analysis (COA)

Lot/Batch Number
MKBT7930V
MKBR3124V
MKBL7562
MKBK1006
MKBH3059

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Naoto Utsumi et al.
Organic letters, 10(16), 3405-3408 (2008-07-18)
Direct organocatalytic Mannich-type reactions of thioesters provide for the expedient and diastereoselective synthesis of protected beta-amino acids. A variety of thioesters were found to be reactive with different imines under mild conditions to provide beta-amino acids in good yields. This
Matthew O'Reilly et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 6092-6095 (2010-05-08)
With the new chiral phosphine ligand DBUP, obtained from DBU and Ph(2)PCl, a remarkable anion effect was observed on the diastereoselective formation of the bischelated complexes [Ni(DBUP)(2)](X)(n) (X = Cl, Br, n = 2; X = NiCl(4), n = 1)
Ning Zhu et al.
Journal of combinatorial chemistry, 12(4), 531-540 (2010-06-01)
The thiol-disulfide dynamic interchange reaction mediated by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) was extensively studied. By this synthetic method sulfides can be prepared successfully within seconds in high yields at room temperature from stable and readily available disulfides and an alkylating agent. The
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