717460
Chloro[tri(o-tolyl)phosphine]gold(I)
95%
Synonym(s):
[Tri(2-methylphenyl)phosphine]gold(I) chloride
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About This Item
Empirical Formula (Hill Notation):
C21H21AuClP
CAS Number:
Molecular Weight:
536.78
UNSPSC Code:
12352300
PubChem Substance ID:
MDL number:
InChI
1S/C21H21P.Au.ClH/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;;/h4-15H,1-3H3;;1H/q;+1;/p-1
SMILES string
Cl[Au].Cc1ccccc1P(c2ccccc2C)c3ccccc3C
InChI key
VECXLHSTZNCQLD-UHFFFAOYSA-M
assay
95%
form
solid
reaction suitability
core: gold, reagent type: catalyst
Application
Catalyst for:
- Alkylation of silyl enol ethers with orthoalkynylbenzoic acid esters
- Cycloisomerization
- Cyclization of 1,6-enynes
- Tandem [3,3]-sigmatropic rearrangement-cycloisomerization cascade
- Cycloaddition of enyne derivatives with aryl alkynes or alkenes
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Regulatory Information
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