720143
Potassium hydroxide on alumina
Synonym(s):
KOH on alumina
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About This Item
Empirical Formula (Hill Notation):
HKO
Molecular Weight:
56.11
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352301
MDL number:
Form:
powder
InChI
1S/K.H2O/h;1H2/q+1;/p-1
SMILES string
[OH-].[K+]
InChI key
KWYUFKZDYYNOTN-UHFFFAOYSA-M
form
powder
mp
>300 °C
Application
Potassium hydroxide on alumina (KOH/AL2O3) can be employed as a base catalyst:
- For the dehydrogenation of cyclic hydrocarbons (cycloolefins, cycloparaffins, and alkyl aromatics).
- To prepare pyridazine derivatives from 1,2-dicarbonyls, and hydrazine hydrate under microwave (MW) irradiation.
- In the total synthesis of natural product (-)-varitriol and (-)-3′-epi-varitriol (an isomer of (-)-varitriol) as potent antitumor agents.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1A
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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The synthesis of (-)-varitriol and (-)-3?-epi-varitriol via a Ramberg-Backlund route
McAllister GD, et al.
Tetrahedron, 63(49), 12123-12130 (2007)
Gas phase base-catalyzed dehydrogenations of cyclic hydrocarbons over a KOH/Al2O3 catalyst
Neumann R and Sasson Y
J. Mol. Catal., 35(1), 131-136 (1986)
Potassium hydroxide impregnated Alumina (KOH-Alumina) as a recyclable catalyst for the solvent-free multicomponent synthesis of highly functionalized substituted pyridazines and/or substituted pyridazin-3 (2H)-ones under microwave irradiation
Mecadon H and Myrboh B
ISRN Organic Chemistry, 2011(1), 131-136 (2011)
Mizuki Takemoto et al.
PloS one, 10(6), e0131094-e0131094 (2015-06-27)
Channelrhodopsin (ChR) is a light-gated cation channel that responds to blue light. Since ChR can be readily expressed in specific neurons to precisely control their activities by light, it has become a powerful tool in neuroscience. Although the recently solved
Ashok R Patel et al.
Journal of agricultural and food chemistry, 63(19), 4862-4869 (2015-05-02)
The aim of this study was to use a detailed rheological characterization to gain new insights into the gelation behavior of natural waxes. To make a comprehensive case, six natural waxes (differing in the relative proportion of chemical components: hydrocarbons
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